Search results for " Weathering"
showing 10 items of 43 documents
Theoretical study on the decomposition mechanism of bisphenol A polycarbonate induced by the combined effect of humidity and UV irradiation.
2020
Polycarbonate (PC) is a good material for covering and protecting cultural heritage sites because of its durability, mechanical properties, and transparency. When bisphenol A polycarbonate is subjected to weathering conditions this polymer shows several degradation processes depending on the irradiation wavelength, humidity and temperature. In particular, the combined effects of humidity and UV irradiation speed up the PC molecular weight reduction. In this work, the decomposition mechanisms associated to the hydrolysis process are scrutinized and the effects of UV irradiation on the hydrolysis process are evaluated throughout the Density Functional Theory (DFT) approach. It was found that …
Soil development on sediments and evaporites of the Messinian crisis
2020
Abstract Vast areas in the Mediterranean are characterised by evaporite deposits of the Messinian crises (c. 6–5.3 Ma BP). During this period, large deposits were built up in shallow lagoon-like systems and are now found in southern Italy, Albania, Cyprus and Turkey. So far, soil formation on evaporites has been studied predominantly in subarid to arid environments. Although the formation of soils has received new significance, little is known about the evolutional trajectories on evaporites of the Mediterranean. We therefore studied soil formation in the Caltanissetta basin (Sicily) where evaporites are most widespread. The lithologies included the sequence: marine clay deposits, laminated…
Disambiguating the soils of Mars
2020
Abstract Anticipated human missions to Mars require a methodical understanding of the unconsolidated bulk sediment that mantles its surface, given its role as an accessible resource for water and as a probable substrate for food production. However, classifying martian sediment as soil has been pursued in an ad hoc fashion, despite emerging evidence from in situ missions for current and paleo-pedological processes. Here we find that in situ sediment at Gusev, Meridiani and Gale are consistent with pedogenesis related to comminuted basalts mixing with older phyllosilicates – perhaps of pluvial origin – and sulfates. Furthermore, a notable presence of hydrated amorphous phases indicates signi…
Prediction of Soil Formation as a Function of Age Using the Percolation Theory Approach
2018
Recent modeling and comparison with field results showed that soil formation by chemical weathering, either from bedrock or unconsolidated material, is limited largely by solute transport. Chemical weathering rates are proportional to solute velocities. Nonreactive solute transport described by non-Gaussian transport theory appears compatible with soil formation rates. This change in understanding opens new possibilities for predicting soil production and depth across orders of magnitude of time scales. Percolation theory for modeling the evolution of soil depth and production was applied to new and published data for alpine and Mediterranean soils. The first goal was to check whether the e…
Black shale deposition during Toarcian super-greenhouse driven by sea level
2013
Abstract. One of the most elusive aspects of the Toarcian oceanic anoxic event (T-OAE) is the paradox between carbon isotopes that indicate intense global primary productivity and organic carbon burial at a global scale, and the delayed expression of anoxia in Europe. During the earliest Toarcian, no black shales were deposited in the European epicontinental seaways, and most organic carbon enrichment of the sediments postdated the end of the overarching positive trend in the carbon isotopes that characterises the T-OAE. In the present study, we have attempted to establish a sequence stratigraphic framework for Early Toarcian deposits recovered from a core drilled in the Paris Basin using a…
Rare earth element and neodymium isotope tracing of sedimentary rock weathering
2020
Chemical weathering plays an important role in sequestering atmospheric CO2, but its potential influence on global climate over geological timescales remains debated. To some extent, this uncertainty arises from the difficulty in separating the respective contribution of sedimentary and crystalline silicate rocks to past weathering rates in the geological record; two types of rocks having presumably different impact on the long-term carbon cycle. In this study, we investigate the use of rare earth element (REE) and neodymium isotopes (εNd) in leached iron oxide fractions of river sediments for tracing the origin of weathered rocks on continents. A new index, called ‘concavity index’ (CI), i…
Paleoclimate and extensional tectonics of short-lived lacustrine environments. Lower Cretaceous of the Panormide Southern Tethyan carbonate platform …
2017
Abstract Subaerial erosion and continental sedimentation interbedded with shallow-water carbonates are unequivocal stratigraphic records to evaluate paleoenvironmental and paleoclimate evolution of emerged landmass. Stratigraphic analysis of the Cretaceous Monte Gallo section of the Mesozoic Panormide carbonate platform, in the northern side of the Palermo Mountains (NW Sicily) records a peculiar continental-derived clays that interrupted the shallow-water carbonate sedimentation. These clays rest, with lenticular geometries, above the tectonically-enhanced subaerial erosional unconformity of the Barremian-Lower Aptian Requienid limestones and are covered by the Upper Cretaceous Rudistid li…
Late Cretaceous continental weathering evolution on the southern Atlantic margins of Africa and South America : contributions of a new geochemical tr…
2022
The late Cretaceous records a pronounced decrease in temperatures on a global scale between 90 and 65 million years that marks the first step of the progressive climatic decline ultimately leading to our modern climate mode. This first cooling step is concomitant to a major tectonic uplift of the east South American and west African margins. Relief formation on the African ans South American continent, enhancing continental weathering, can have induced a climatic cooling at a global scale through atmospheric CO2 consumption linked to silicate weathering reactions. The main objective of this project is to explore the potentially determinant impact of this tectonic uplift on the long-term coo…
The role of hydrology on enhanced weathering for carbon sequestration I. Modeling rock-dissolution reactions coupled to plant, soil moisture, and car…
2021
Abstract Enhanced Weathering (EW) resulting from soil amendment with highly reactive silicate minerals is regarded as one of the most effective techniques for carbon sequestration. While in laboratory conditions silicate minerals dissolution rates are well characterized, in field conditions the rate of the dissolution reaction is more difficult to predict, not least because it interacts with soil, plant, and hydrologic processes. Here we present a dynamic mass balance model connecting biogeochemical and ecohydrological dynamics to shed light on these intertwined processes involved in EW. We focus on the silicate mineral olivine, for its faster laboratory dissolution rate, and pay particular…
Origin of clay minerals in soils on pyroclastic deposits in the island of Lipari (Italy)
2005
The island of Lipari (Italy) is characterized by calc-alkaline to potassic volcanism and a Mediterranean-type climate. The mineralogical and chemical features of two different soil profiles with ages of 92,000 and 10,000–40,000 y, respectively, have been investigated. There were no Andisols, but Vitric and Vertic Cambisols have developed at both sites. Although the morphology of the soils was similar, remarkable differences in the clay mineralogy between the two sites were observed. The site with the Vitric Cambisol was associated with the weathering sequence: glass → halloysite → kaolinite or interstratified kaolinite-2:1 clay minerals. Both sites had smectite in the clay fraction and, to …